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  Advanced Spectroscopic Techniques for Separating Natural and Synthetic Diamond Gemstones


   Cardiff School of Physics and Astronomy

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  Dr Georgina Klemencic, Dr S Lynch  No more applications being accepted  Funded PhD Project (UK Students Only)

About the Project

Knowing the origin or provenance of a diamond gemstone with certainty is critical to determining its value. This question goes deeper than whether the diamond is of synthetic or natural origin. Information about a gemstone’s provenance is increasingly important in reassuring the consumer that their diamond has been ethically sourced and that best practice has been maintained throughout its production.

 Synthetic gemstone-quality diamond material can now be produced by high pressure high temperature (HPHT) or chemical vapor deposition (CVD) growth methods. However, since natural untreated diamonds are valued above treated diamonds or synthetics, customers need to be convinced that undisclosed synthetics can be detected with a high degree of confidence. One of the most powerful analytical weapons in the gemmologist’s armoury is optical spectroscopy because it can record the optical characteristics of a gemstone in a quantifiable and reproducible way. The technique is also inherently non-destructive. Certain optical signatures will raise suspicion by indicating the presence of additional elements, or point and extended defects, not commonly found in natural diamonds. Likewise, certain optical signatures can reveal clues about the growth conditions when the crystal was forming, conditions that will be significantly different for natural and synthetic diamonds. As the quality of synthetic diamond gemstones continues to improve, it is increasingly important to develop more advanced spectroscopic interrogation techniques to keep ahead.

 This project will be supervised by Dr Georgina Klemencic (Cardiff), Dr Stephen Lynch (Cardiff) and Dr Colin McGuinness (De Beers). Cardiff University and De Beers have previously worked closely together to understand unusual spectral signatures that were found in synthetic gemstones. This project will build on the legacy of this work. We are seeking a student to continue to develop a spectroscopic imaging experiment able to explore the luminescence behaviour of diamond under pulsed ultraviolet illumination over a range of timescales and temperatures. It is expected that the student will spend up to 6 weeks per year at De Beers research laboratories in Maidenhead validating their work. This PhD project thus provides an exciting opportunity to perform cutting-edge physics research that is also industrially relevant. While working at De Beers, the student will receive unique bespoke training and they will be able to experience the research and development environment in a multinational company.

 Interested parties may read more about this work in this open-access article in Gems & Gemmology.

 Applicants should hold, or expect to receive, a First Class or high Upper Second Class UK Honours degree (or the equivalent qualification gained outside the UK) in Physics, Materials Science, or a related subject, and should have an interest in experimental physics/instrumentation and spectroscopy. A master’s level qualification would also be advantageous.

Applicants whose first language is not English are normally expected to meet the minimum University requirements (e.g. 6.5 IELTS) (https://www.cardiff.ac.uk/study/international/english-language-requirements)

Applicants should apply to the Doctor of Philosophy in Physics and Astronomy with a start date of 1st October 2022 (3.5 years programme).

Applicants should submit an application for postgraduate study via the Cardiff University webpages (https://www.cardiff.ac.uk/study/postgraduate/research/programmes/programme/physics-and-astronomy) including:

• your academic CV

• a personal statement/covering letter

• two references, at least one of which should be academic

• Your degree certificates and transcripts to date.

In the "Research Proposal" section of your application, please specify the project title and supervisors of this project.

In the funding section, please select that you will not be self funding and write that the source of funding will be EPSRC.

Please note: We may close this advert early if we find a suitable candidate before the application deadline.

Physics (29)

Funding Notes

The studentship is for 3.5 years and covers tuition fees, an annual tax-free living stipend of £16,062 (subject to change) and includes access to a Research Training Support Grant (currently £4000).
This EPSRC studentship is available to home students. Applicants should satisfy the UKRI eligibility requirements.

References

Separation of Natural from Laboratory-Grown Diamond Using Time-Gated Luminescence Imaging
http://dx.doi.org/10.5741/GEMS.56.2.220

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