University of Birmingham Featured PhD Programmes
University of Liverpool Featured PhD Programmes
Catalysis Hub Featured PhD Programmes
University of Kent Featured PhD Programmes
Brunel University London Featured PhD Programmes

Dithizone as a source of unusual nitrogen-rich ligands

  • Full or part time
  • Application Deadline
    Applications accepted all year round
  • Self-Funded PhD Students Only
    Self-Funded PhD Students Only

Project Description

There is currently much interest in nitrogen-rich ligands both as intriguing species in their own right and as potential high energy density materials. We suspect that unusual nitrogen-containing rings and chains might best be prepared in the coordination sphere of transition metals. The compound dithizone, PhN=NC(=S)NHNHPh, known for years as an analytical reagent, forms a cyclic mesoionic tetrazole thione (PhNN)2C=S when oxidized. Previous work in our lab has studied the reactions of thiones with various organometallic complexes and shown that processes involving dimerisation by loss of sulfur, C=S bond cleavage, and opening of heterocyclic rings are all possible. We therefore expect that when treated with an appropriate organometallic complex, the tetrazole thione ring will serve as the source for a variety of novel nitrogen-containing ligands.
This project is primarily organometallic chemistry with some organic synthesis.

Funding Notes

Self- Funded

Email Now

Insert previous message below for editing? 
You haven’t included a message. Providing a specific message means universities will take your enquiry more seriously and helps them provide the information you need.
Why not add a message here
* required field
Send a copy to me for my own records.

Your enquiry has been emailed successfully

FindAPhD. Copyright 2005-2019
All rights reserved.