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Multifunctional Metal Organic Framework Catalysts for Organic Transformations


Project Description

Metal Organic Frameworks (MOFs) have great potential within heterogeneous catalysis for fine chemicals synthesis, which derives from their high and controllable porosity and their great chemical versatility. This multi-disciplinary PhD project, which is a collaboration with Glaxo Smith-Kline (GSK), builds on our recent discovery that certain MOFs can readily be decorated with ‘tagged’ molecular catalysts or catalytic ligands (Prasad et al. Chem. Eur. J. 2018, 24, 15309). We aim to explore new tandem transformations that make use of the multi-functional MOF catalysts we are preparing, and to determine the structure-performance relationship for these catalysts by quantitative approaches. This timely development of new materials can make a significant impact upon the synthesis of pharmaceutical intermediates.
The successful candidate need not already have the broad range of skills and experience that will be called on, but will possess a strong interest in carrying out research across different research areas. As well as researching the synthesis, structural characterisation and performance testing of MOF catalysts, the candidate will gain experience in modelling the kinetic results.

All aspects of the project will be supervised by an experienced academic and industrial team. As well as being an enjoyable and fascinating area of current research, this iCASE PhD will provide an ideal stepping-stone towards a career in either academia or the chemical industry.
The School of Chemistry https://www.st-andrews.ac.uk/chemistry/ provides an excellent environment for research and study. The research will take place in both a synthetic chemistry and catalysis laboratory (M. L. Clarke) and a materials research laboratory (P. A. Wright) and will include project meetings and extended research visits to GSK Stevenage. The School has extensive NMR (solution- and solid-state) and MS facilities, and a range of materials characterisation techniques, including diffraction, electron microscopy, porosimetry and access to molecular modelling.

Funding Notes

Eligibility requirements: UK student with a First or 2.1 degree in Chemistry or related subject.
Funding source: EPSRC/GSK
Duration: up to 4 years
Start Date: September 2019

How good is research at University of St Andrews in Chemistry?
(joint submission with University of Edinburgh)

FTE Category A staff submitted: 37.30

Research output data provided by the Research Excellence Framework (REF)

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