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  From Farm to Coast: Fluxes and isotopic fingerprints of greenhouse gases in river catchments, estuaries and coastal waters (CASE studentship with SERCON Ltd) (REESUPML18EE)


   School of Environmental Sciences

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  Dr Andrew Rees, Prof Jan Kaiser, Dr Helen Atkinson, Dr V Kitidis  No more applications being accepted  Competition Funded PhD Project (European/UK Students Only)

About the Project

Scientific background
Nitrous oxide (N2O) and methane (CH4) are potent greenhouse gases, which play a part in the depletion of stratospheric ozone and the oxidative capacity of the atmosphere. Despite this importance, the quantification of sources and sinks of these gases and their transport in rivers, inland waters, estuaries and coasts are poorly constrained.

Research methodology
This project will use state of the art instrumentation to determine concentrations and the stable isotopic signatures (15N, 13C) of N2O and CH4 in streams, rivers, estuaries and coastal waters in southwest England. A sense of adventure is required to deliver a sampling programme using small boats and larger research vessels, which will be embedded in the NERC research programme LOCATE (http://locate.ac.uk/). You will determine seasonal and spatial variability in concentrations and fluxes between river catchment and coastal seas, and use stable isotopes to help elucidate the complex biological, chemical and physical transformations occurring, taking into account factors including nutrient loading, oxygen status and residence times.

Training
You will receive specialist training in the measurement of stable isotopes 15N and 13C using continuous-flow stable isotope mass spectrometry and the use of gas chromatography and cavity ring down spectroscopy to determine gas concentrations. This will be coupled to broader training in the biogeochemistry of riverine, estuarine and coastal systems. You will also be trained in professional skills, including attendance at UK and international summer schools and conferences.

Research Environment
You will spent most of your time with Drs Rees and Kitidis in recently refurbished laboratories at PML, with easy access to the River Tamar and the English Channel, but will also work for shorter periods with co-supervisors Kaiser at UEA and Atkinson at partner Sercon. At all locations, you will be embedded in dynamic teams investigating marine biogeochemistry and related stable isotope applications.

Requirements
We seek an enthusiastic, self-motivated candidate, with a strong aptitude for practical work and intensive field campaigns on small boats. You will have at least a 2.1 BSc in chemistry, physics, oceanography or a suitable branch of environmental sciences.
EnvEast welcomes applicants from quantitative disciplines who may have limited background in environmental sciences. Excellent candidates will be considered for an award of an additional 3-month stipend to take appropriate advanced-level courses in the subject area.

This project has been shortlisted for funding by the EnvEast NERC Doctoral Training Partnership, comprising the Universities of East Anglia, Essex and Kent, with over twenty other research partners. Undertaking a PhD with the EnvEast DTP will involve attendance at mandatory training events throughout the course of the PhD.

Shortlisted applicants will be interviewed on 12/13 February 2018.

For further information, please visit www.enveast.ac.uk/apply.


Funding Notes

Successful candidates who meet RCUK’s eligibility criteria will be awarded a NERC studentship - in 2017/18, the stipend is £14,553. In most cases, UK and EU nationals who have been resident in the UK for 3 years are eligible for a stipend. For non-UK EU-resident applicants NERC funding can be used to cover fees, RTSG and training costs, but not any part of the stipend. Individual institutes may, however, elect to provide a stipend from their own resources.

References

(i) Grefe, I. and Kaiser, J. (2014) Equilibrator-based measurements of dissolved nitrous oxide in the surface ocean using an integrated cavity output laser absorption spectrometer. Ocean Science, 10 (3). pp. 501-512. ISSN 1812-0784

(ii) Rees, A. P., I. J. Brown, D. R. Clark, and R. Torres (2011). The Lagrangian progression of nitrous oxide within filaments formed in the Mauritanian upwelling, Geophys. Res. Lett., 38, L21606, doi:10.1029/2011GL049322.

(iii) Kitidis, V., Tizzard, L., Uher, G., et al.The biogeochemical cycling of methane in Ria de Vigo, NW Spain: Sediment processing and sea-air exchange . 2007. 66 (1-4), 258-271.

(iv) Borges A.V. et al. 2017. Effects of agricultural land use on fluvial carbon dioxide, methane and nitrous oxide concentrations in a large European river, the Meuse (Belgium). Science of The Total Environment 610–611, 342–355, DOI: 10.1016/j.scitotenv.2017.08.047

(v) Bakker D.C.E. et al., 2014. Air-Sea Interactions of Natural Long-Lived Greenhouse Gases (CO2, N2O, CH4) in a Changing Climate. P.S. Liss and M.T. Johnson (eds.), Ocean-Atmosphere Interactions of Gases and Particles, Springer Earth System Sciences, DOI 10.1007/978-3-642-25643-1_3

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