Sandwich complexes of the f-elements as high-temperature single-molecule magnets

The project falls broadly into the research field of organometallic chemistry, with a specific focus on the structure, bonding, reactivity and magnetism of f-block sandwich complexes. The project will build on recent ground-breaking results from the Layfield group (see recent publication in Science) in which the first single-molecule magnet (SMM) to show hysteresis above liquid-nitrogen temperatures was described. For the new project, we will extend these findings to new systems based on the ‘sandwich’ structural motif involving lanthanides and uranium. The primary aim of the project is to develop new molecular magnets in which the electronic structure can be modified in a controlled way through synthetic organometallic chemistry, ultimately expanding the family of high-temperature SMMs.

Interested candidates are strongly encouraged to email Prof. Layfield to discuss the project further.

How to apply:
Please submit a formal application using our online application system at http://www.sussex.ac.uk/study/phd/apply, including a CV, degree transcripts and certificates, statement of interest and names of two academic referees. On the application system use Programme of Study – PhD Chemistry.
The project will not show on the application system. Please ensure you put a name of the supervisor in the proposed supervisor section. In the personal statement clearly state the project title.

For enquiries about the application process contact Anna Izykowska ([Email Address Removed])
For enquiries about the project contact Professor Layfield ([Email Address Removed])