Catalytic Remote Functionalization of Hydrocarbons

Name of Supervisor: Prof Ruben Martin

More information: http://www.iciq.org/research/research_group/prof-ruben-martin/

Description of the project:
Metal-catalysed cross-coupling reactions have changed the landscape of organic synthesis. In these processes, bond-construction typically occur via functional group interconversion of pre-existing functionalities. This project will deal with the development of earth-abundant catalysts for promoting a variety of C-C and Cheteroatom bond-forming reactions at remote and previously unfunctionalized positions within a hydrocarbon side-chain. The study of the mechanism by which these reactions operate will also be conducted, either by kinetic experiments or at the molecular level by the isolation of the putative reaction intermediates.

Preferred skills or background:
The candidate should have a strong background and proven track record in organometallic chemistry with considerable experience with the optimization of catalytic reactions and excellent Schlenk techniques when dealing with air- and moisture-sensitive species. It is necessary to have a proven good knowledge of English.