About the Project
We have previously worked on the synthesis of a range of selenium rich systems. This project will involve studying the synthesis and coordination chemistry of seleno compounds with a view to understanding their reactivity, structure and potential biological activity
Techniques to be used..Synthesis, multinuclear nmr, crystallography.
We would be willing to consider applicants who wish to specialise in synthesis or X-ray crystallography.
We have world leading facilities for crystallography.
References
New P-Se compounds from the reaction of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide with alkyl-diols, G. Hua, Y. Li, A. M. Z. Slawin and J. D. Woollins, Tetrahedron, 2008, 64, 5442–5448. doi:10.1016/j.tet.2008.04.017
Synthesis and Structure of 8-, 9- and 10-membered rings with P-Se-Se-P linkages’ G Hua, Y Li, A M. Z. Slawin and J. D Woollins, Angew. Chem.Int Ed Engl, 2008,47, 2857-2859.
Formation and Reactivity of Phosphorus-Selenium Rings G. Hua and J. D Woollins, Angew. Chem.Int Ed Engl, 2009, 48, 1368-1377.DOI: 10.1002/anie.200800572